Arsenic is a major concern for both drinking water and household water 

Health Effects of Arsenic

Arsenic Occurrence in the United States

Arsenic Removal with AD33

History of Arsenic Legislation

 

Health Effects of Arsenic

Throughout history, arsenic has been used as a poison.  One of the earliest documented cases of arsenic poisoning was Nero’s poisoning of Brittannicus to secure the Roman throne in 55 A.D.  French scientists believe that French and British conspirators poisoned Napoleon with arsenic.  In the winter of 1609-1610, more than 90 percent of the Jamestown colony perished.  Many scientists believe the deaths were the result of arsenic poisoning at the hands of the Spanish government intent on getting rid of the English colony.

Today, arsenic continues to poison millions of Americans.  The element occurs naturally in the soil and enters the water supply throughout the U.S., especially in the west, mid-west and New England.  After more than 20 years of debate, a new arsenic standard was signed into law in late 2001, reducing the allowable level for the contaminant in drinking water by more than 80%.  The law impacts 4,100 public water systems that serve 13 million people.  An additional 40 million Americans obtain their water from private wells, which are not protected by the new standard and may have high levels of arsenic.  Even at the new level of 10 parts per billion (ppb), three in 1,000 people exposed will die from cancer.  For the past two decades, the EPA’s maximum acceptable level of risk for all other drinking water contaminants has been one in 10,000.

Click here to see the health effects and symptoms of arsenic exposure

Arsenic Removal with AD33

Up until the past year, three basic alternatives have been commercially available for arsenic reduction for POE: Activated alumina adsorption, Anion Exchange, and Reverse Osmosis.   The most common alternatives implemented have been anion exchange and RO.  Up until now, use has been fairly limited for several reasons: relatively little awareness of the toxicity of arsenic, high relative cost, and low demand.  Adsorption using the Adedge high capacity iron oxide based media is rapidly filling the need generated by consumer awareness. The AD33 is quickly emerging as the best alternatives for whole household treatment of arsenic.  Each technology has advantages and disadvantages.  Click here to learn more about AD33.

AD33 is a "dry" granular iron oxide media. The iron hydroxide granules, specially developed in tandem by Bayer AG and Severn Trent Water (UK) for the removal of arsenic from drinking water, are distinguished against other adsorptive media by their finely structured surfaces in the nano range which adsorb the arsenic. Another strong benefit of the AD33 is the fact that it is a "dry" material, unlike other competing iron medias this material provides operators a much easier and safer means of handling. The tremendous ability of the media to remove arsenic and it's dry form allows for a more diverse range of products. The following table summarizes some of the pros and cons of the commercial options.

Point of Entry Treatment for Arsenic

Feature

Anion Exchange

Reverse Osmosis

AD33 Iron Oxide Adsorption

 Type of arsenic treated

As (V)

As (V) 

As (V) and (III)

Pre-oxidation step required  for As removal

Yes

Yes

No

 Chemical Use

Salt

Membrane cleaning

No

 Loss (waste) of water

5%

25-75%

< 1%

 Frequency of   Regeneration

Approx. every 2000-4,000 gallons

 Not Applicable

Non regenerable, replace media after 2-4 years

 Hazardous waste generation

Yes

Concentrated arsenic reject

None

 Off-taste potential

Yes

No

No

 Maintenance

High

High

Low

 Arsenic “dumping”

Possible

No

No

Interferents or pretreatment needs

TSS, sulfate,  iron,  organics, tannins

TSS, Iron, manganese, silica, tannins

Iron, sulfides, phosphate, tannins

Capital Cost  to end user

ESTIMATES ONLY

(incl preoxidation*)

Moderate

$1500-3500*

High

$9,000-15,000*

Moderate

$1750-2500

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Arsenic Occurrence in the United States

The United States Geological Survey has compiled the following map of arsenic in drinking water in the United States.

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The History of Arsenic Regulation

 Arsenic Legislatve Timeline 

Date

Action

1942

The drinking water standard was set at 50 parts per billion (ppb) by the U.S Public Health Service.

1975

This standard was adopted by the U.S Environmental Protection Agency (EPA)  as a result of the passage of the Safe Drinking Water Act. 

1989

COntroversy around health effects studies caused postponement of final rule until November, 1992

November 1992

The EPA, citing the need to further to evaluate health effects, postponed the final rule until September 1994

September 1994

Due to a delay in the EPA studies, the final rule was postponed until November 1995.

November 1995

Due to Congressional concerns, including cost of implementing a solution, the final rule was postponed until January 2000,

June 2000

New rule proposal isued with final rule date of Jun22, 2001

January 2001

The EPA posted a final rule in the Federal Register, five months ahead of schedule, lowering the standard from 50 to 10 ppb.  The EPA also established a health-based, non-enforceable Maximum Contaminant Level Goal (MCLG) for arsenic of 0 ppb. 

March 2001

Under the new leadership of the Bush administration the EPA withdrew the rule. They stated that more research on cost and health effects was needed.  The effective date of the new rule was delayed until May 22, 2001. 

May 2001

The effective date was delayed again by the EPA, until February 22, 2002, stating a need for public reaction and additional research.  Studies on the benefits of a new standard, cost expectations and health effects were commissioned by the agency.  Even though under the Bush administration, the EPA refused to implement the final rule of 10 ppb, they publicly acknowledged that the standard needed to be lowered somewhere between 3 and 20 ppb. 

August  2001

Reports of the study and suggestions of the Arsenic Cost Working Group were concluded by the National Drinking Water Advisory (NDWAC) and delivered to the EPA.  The NDWAC stated that a valid evaluation of the cost of compliance was presented by the EPA, but that other treatment options, like Point-of-Use, could possibly allow smaller water systems to conform more cost-effectively. 

August  2001

The final report on the benefits of a lowered standard was given by the Science Advisory board (SAB) to the EPA.

September 2001

The results of the health effects study was released by the National Adademy of Sciences (NAS).  It was reported that the dangers of cancer are much higher than they had been previously reconized under the Clinton and Bush administrations. 

October 2001

The EPA released information on and availability of three reports ­ the health effects/science report prepared by the National Academy of Sciences, the costs report of the National Drinking Water Advisory Council, and the benefits report of the EPA’s Science Advisory Board.  These reports can be viewed online at:

NAS health effects report:

http://www.nap.edu/books/0309076293/html/

NDWAC costs report:

http://www.epa.gov/safewater/ars/ndwac-arsenic-report.pdf

SAB benefits report:

http://www.epa.gov/sab/ec01008.pdf 

October  2001

EPA announces call for public comment on the three reports by October 31, 2001.

November 2001

Official announcement by the EPA that it would lower the arsenic standard from 50 ppb to 10 ppb. 

November 2001

The bill for the new arsenic standard of 10 ppb  was signed by President George W. Bush.  Public water systems were given until 2006 to comply with the new rule.

References

The EPA’s Office of Research and Development may have also discovered a link to DNA damage caused by arsenic compounds.  The research shows arsenic inducing a reaction between itself and DNA, causing certain genetic alterations in the DNA that result in breakage.

The following links are references to some current research projects on the health effects of arsenic:

www.epa.gov/safewater/arsenic.html

http://socrates.berkeley.edu/~asrg/

More references and papers presented on the health effects of arsenic exposure that can be accessed at a library.

Click here to see a list of references

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Arsenic Information  

 

 

This information provided by Adedge Technologies